The value of _pdbx_reference_molecule_list.prd_id is the unique identifier for the reference molecule in this family.
By convention this ID uniquely identifies the reference molecule in in the PDB reference dictionary.
The ID has the template form PRD_dddddd (e.g. PRD_000001)
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The value of _pdbx_reference_molecule_list.family_prd_id is a reference to _pdbx_reference_molecule_family.family_prd_id' in category PDBX_REFERENCE_MOLECULE_FAMILY.